Accession Number : AD0264819

Title :   THE CRYSTAL STRUCTURE OF SBC15.SO(C6H5)2

Corporate Author : UPPSALA UNIV (SWEDEN)

Personal Author(s) : HANSSON,ARNE ; VANNGARD,MARGARETA

Report Date : 20 APR 1961

Pagination or Media Count : 1

Abstract : The crystal structure of SbCl5.SO(C6H5)2 was determined from 3-dimensional X-ray data. The crystals were prepared from a mixture of a solution of 0.40g (C6H5)2SO dissolved in 30 ml CCl4 and a solution of 0.25 ml SbCl5 in 30 ml CCl4. The structure was made up of SbCl5.SO(C6H5)2 molecules, and coordination around the Sb atom was octahedral. The O and Sb atoms in (C6H5)2SO and SbCl5 functioned as donor and acceptor atoms, respectively. Coordinate, bond angle, and molecular distance data are given. The bond between the O and Sb atoms was weak. The stability of the addition compound was attributed to secondary effects.

Descriptors :   *ANTIMONY COMPOUNDS, *CHLORIDES, *CRYSTAL STRUCTURE, *CRYSTALS, *PHENYL RADICALS, *SULFOXIDES, CARBON TETRACHLORIDE, CHEMICAL BONDS, COMPLEX COMPOUNDS, MEASUREMENT, MOLECULAR ASSOCIATION, SOLUTIONS(MIXTURES), STABILITY, SYNTHESIS, X RAY DIFFRACTION

Distribution Statement : APPROVED FOR PUBLIC RELEASE