Accession Number : AD0373367
Title : SYNTHESIS OF LMH-2.
Descriptive Note : Quarterly progress rept. no. 1, 4 Jan-3 Apr 66,
Corporate Author : UNITED STATES INDUSTRIAL CHEMICALS CO CINCINNATI OHIO
Personal Author(s) : Murib,Jawad H.
Report Date : MAY 1966
Pagination or Media Count : 18
Abstract : Beryllium hydride in purities up to 87.5 wt.% was obtained from the disproportionation of ClBeH:OEt2 in dimethylsulfide at 25 C. The purity of the CBH disporportionation product obtained in 1,2-dichloroethane was improved to 66.3 wt.% BeH2 over a previous value of 34.1%. Under certain conditions the ratio of active H to residual Cl reached 143/1 corresponding to a purity of 95 wt.% BeH2 based on residual BeCl2 as the only contaminant. The products were amorphous to X-ray. Retained ether remains a major contaminant. Complete removal of retained ether by thermal means could not be accomplished without causing some cleavage. Chemical methods are being investigated to displace the residual ether. (Author)
Descriptors : (*HYDRIDES, METALS), PURIFICATION, SOLUBILITY, DISPROPORTIONATION, REACTION KINETICS, THERMAL PROPERTIES, X RAY DIFFRACTION, CHEMICAL CONTAMINATION (U) BERYLLIUM, CHLORIDES, SODIUM COMPOUNDS, BENZENES, AMINES, ETHERS, ROCKET PROPELLANTS
Subject Categories : Rocket Propellants
Distribution Statement : APPROVED FOR PUBLIC RELEASE