Accession Number : AD0373785

Title :   THE PROPERTIES OF A NEW ACRYLIC MONOMER,

Corporate Author : ROHM AND HAAS CO HUNTSVILLE ALA REDSTONE RESEARCH LABS

Personal Author(s) : Johnson,Kenneth E.

Report Date : 08 JUL 1966

Pagination or Media Count : 45

Abstract : The kinetics of free radical homopolymerizations and copolymerizations ofNFPA in solution have been measured and the corresponding rate constants and reactivity ratios have been determined. These rate studies and characterizations of resulting polymers have resulted in rather complete descriptions of the polymerization of NFPA. Poly NFPA is a rubbery polymer having physical and dilute solution properties sililar to those of other alkyl arcylates. Copolymers of NFPA with other acrylic monomers containing hydroxy, carboxy, epoxy, anhydride, and acid groups were prepared in solution. These functional groups were used as handles for crosslinking the copolymers through difunctional reagents. Significant and somewhat expected changes in physical properties were observed as these comonomers were incorporated into NFPA polymers. Molecular weight and intrinsic viscosity relationships for polymers of NFPA have been defined. (Author)

Descriptors :   (*SOLID ROCKET PROPELLANT BINDERS, *ACRYLIC RESINS), INHIBITION, POLYMERIZATION, REACTION KINETICS, COPOLYMERIZATION, MOLECULAR WEIGHT, VISCOSITY, INFRARED SPECTRA, MOLECULAR STRUCTURE, SYNTHESIS(CHEMISTRY), NUCLEAR MAGNETIC RESONANCE, IMPACT TESTS, SENSITIVITY, STORAGE, STABILITY, THERMAL STABILITY, DIFFERENTIAL THERMAL ANALYSIS, ADDITIVES, SOLVENT ACTION, COLLOIDS (U) FLUOROAMINES, CROSSLINKING(CHEMISTRY), OXIDATION REDUCTION REACTIONS

Subject Categories : Solid Rocket Propellants

Distribution Statement : APPROVED FOR PUBLIC RELEASE