Accession Number : AD0376350

Title :   ADVANCED OXIDIZER RESEARCH.

Descriptive Note : Semiannual rept. 1 Jan-30 Jun 66,

Corporate Author : REACTION MOTORS DIV THIOKOL CHEMICAL CORP DENVILLE N J

Personal Author(s) : Young,Archie R. , II ; Dvorak,Joseph

Report Date : 31 JUL 1966

Pagination or Media Count : 27

Abstract : N2F3AsF6 was observed to be compatible with the perchlorates; KClO4, NH4ClO4, and (CH3)4NClO4, in the solid state. Metathesis with perchlorates in liquid sulfur dioxide at -50 C was unsuccessful because of reaction of N2F3AsF6 with the solvent to produce NOAsF6. N2F3AsF6 reacts rapidly with the strongly acidic solvent, HSO3F. Fluorination of Cl2NF over CsF at low temperatures gave only known compounds. The attempted preparation and in situ fluorination of CF3OCl was unsuccessful. The fluorination of a purple Cl2-O2AsF6 adduct at -80 C produced an unidentified volatile product, in addition to ClO3F and oxides of chlorine. No stable adducts could be isolated in the reactions of C-NF2 and C=NF compounds with AsF5 or BF3. Attempts to synthesize N-fluorooxaziranes from ketofluorimines were unsuccessful. CF3OF does not form adducts with AsF5 or BF3. (Author)

Descriptors :   (*OXIDIZERS, SYNTHESIS(CHEMISTRY)), CHEMICAL REACTIONS (U) (*FLUOROAMINES), FLUORINE COMPOUNDS, PERCHLORATES, NITROGEN COMPOUNDS, ARSENIC COMPOUNDS, SPECTRA(INFRARED), IONS, X RAY DIFFRACTION, FLUORINATION, AMMONIUM COMPOUNDS, CESIUM COMPOUNDS, AROMATIC COMPOUNDS, BENZENES, OXIDES, HALOGEN COMPOUNDS

Subject Categories : Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE