Accession Number : AD0377178

Title :   MOLECULAR SUBSTITUTION STUDIES.

Descriptive Note : Quarterly progress rept. 1 Aug-31 Oct 66,

Corporate Author : AEROJET-GENERAL CORP AZUSA CALIF

Personal Author(s) : Hurst,Gerald L. ; Robeson,Ross K. ; Shuey,Harry F. ; Graefe,Allen F.

Report Date : NOV 1966

Pagination or Media Count : 10

Abstract : It is postulated that changing the chemical environment of unstable NF moieties may yield new energetic materials which have desirable properties. Known high-energy species are being used for the synthesis of NF compounds. Reactions involving the mixture of mercurials obtained from FN(Cl)CO2-iPr and Hg with acetyl chloride and with bromine yielded CH3CONFCO2-iPr and FN(Br)CO2-iPr, respectively. Attempts to prepare iPr-O2CNFNFCO2-iPr, and the cations N2F5(+) and C(NF2)3(+) in the form of their SbF6(-) salts were unsuccessful. (Author)

Descriptors :   (*ORGANIC COMPOUNDS, SUBSTITUTION REACTIONS), (*INORGANIC COMPOUNDS, SUBSTITUTION REACTIONS), CHEMICAL COMPOUNDS, SYNTHESIS(CHEMISTRY), CHEMICAL REACTIONS (U) COMPLEX COMPOUNDS, NITROGEN COMPOUNDS, FLUORINE COMPOUNDS, ANTIMONY COMPOUNDS, FREE RADICALS, LIQUID ROCKET OXIDIZERS, IONS, FLUORIDES, BROMINE, ACETIC ACID, CHLORINE, ENERGY, LIQUID ROCKET PROPELLANTS, MERCURY

Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE