Accession Number : AD0431871

Title :   RESEARCH ON NEW OXIDANTS AND MECHANISMS OF OXIDANTS.

Descriptive Note : Semi-annual rept. no. 1, 1 Jun-1 Dec 63,

Corporate Author : PENNSALT CHEMICALS CORP PHILADELPHIA PA

Personal Author(s) : Gardner,D. M.

Report Date : DEC 1963

Pagination or Media Count : 27

Abstract : Reactions of ClO3F with a number of selected organic compounds were studied. The following compounds were not attacked by ClO3F: pyridine, tributyl phosphate, methyl benzilate, dimethyl methylphosphonate, and O,O,S - triethyl phosphorothiolate. Piperidine reacted to form the unstable, explosive N-perchloryl piperidine, the first known member of a new class of organic compounds. N-perchloryl piperidine slowly hydrolyzes in base to isotripiperideine-N-oxide. Dimethyl sulfide reacts violently with ClO3F but the reaction can be controlled by the use of solvents or of low gas flow rates of ClO3F. O,O-Diethyl phosphorodithiolate reacts with ClO3F to form at least two condensed species: an oil and crystals. Triethylene diamine reacts with ClO3F to form an unstable, hygroscopic complex of the type N(C2H4)3NClO3(+)F(-). In contrast triethylamine undergoes an exothermic reaction with ClO3F. (Author)

Descriptors :   (*FLUORINE COMPOUNDS, CHLORINE COMPOUNDS), (*CHLORINE COMPOUNDS, FLUORINE COMPOUNDS), (*OXIDIZERS, FLUORINE COMPOUNDS), PIPERIDINES, NITROGEN HETEROCYCLIC COMPOUNDS, ORGANIC SULFUR COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, COMPLEX COMPOUNDS, ESTERS, SULFIDES, AMINES, SULFOXIDES, PHOSPHATES, PHOSPHONIC ACIDS, PYRIDINES, CHEMICAL REACTIONS, OXIDATION, REACTION KINETICS, MOLECULAR STRUCTURE

Distribution Statement : APPROVED FOR PUBLIC RELEASE