Accession Number : AD0449370

Title :   FAR INFRARED AND RAMAN SPECTRA AND STRUCTURE OF DITHIOPHOSGENE,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF APPLIED CHEMISTRY

Personal Author(s) : Busfield, W. K. ; Taylor, M. J. ; Whalley, E.

Report Date : 02 APR 1964

Pagination or Media Count : 4

Abstract : The infrared spectrum in the range 1/3000 - 1/50 cm and the Raman spectrum of solutions of dithiophosgene were obtained. There are no coincidences in the infrared and Raman spectra, and only structure consistent with this and approximately tetrahedral carbon valencies is that tetrachloro-1,3-dithietane, in which the ring is planar or nearly planar. A tentative assignment of the observed bands is given on the basis of D sub 2h symmetry. (Author)

Descriptors :   *ORGANIC SULFUR COMPOUNDS, *CHLORINE COMPOUNDS, *MOLECULAR SPECTROSCOPY, INFRARED SPECTRA, RAMAN SPECTROSCOPY, MOLECULAR STRUCTURE, CANADA.

Distribution Statement : APPROVED FOR PUBLIC RELEASE