Accession Number : AD0479608

Title :   IONIC REACTIONS IN GASEOUS AMINES.

Descriptive Note : Technical rept.,

Corporate Author : VIRGINIA UNIV CHARLOTTESVILLE

Personal Author(s) : Munson, M. S. B.

Report Date : MAR 1966

Pagination or Media Count : 22

Abstract : Ionic reactions are reported for ammonia and the three methylamines. The major product ions are the protonated molecule ions and the higher solvates of these ions. Proton transfer, charge transfer, and hydride transfer reactions were observed in the tri-methylamine system. The rate constants for ionic reactions in this series of compounds show a slight decrease which parallels the decrease in dipole moment -- NH3<CH3NH2<(CH3)2NH<(CH3)3N -- rather than the increase in polarizability in this sequence. (Author)

Descriptors :   (*IONS, REACTION KINETICS), (*AMINES, GASES), METHANE, COMBUSTION, SOLVATES, DETONATIONS, DIPOLE MOMENTS, SHOCK WAVES, AMMONIA, HYDRIDES, POLARIZATION, PRESSURE, DENSITY, MOLECULAR WEIGHT, HEAT OF FORMATION, STABILITY, ELECTRONS, PROTONS.

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE