Accession Number : AD0483631

Title :   PHOSPHORYL FLUOROSULFATE.

Descriptive Note : Technical rept.,

Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s) : Des Marteau, Darryl D. ; Cady, George H.

Report Date : 20 MAY 1966

Pagination or Media Count : 8

Abstract : This report describes the formation of phosphoryl fluorosulfate. It is formed by the reaction of phosphoryl bromide with an excess of peroxydisulfuryl difluoride. POBr3 + 6S2O6F2 = PO(SO3F)3 + 3Br(SO3F)3. The products may be separated by vacuum distillation.

Descriptors :   *FLUORINE COMPOUNDS), (*PHOSPHORUS COMPOUNDS, (*SULFATES, FLUORINE COMPOUNDS), CHEMICAL PROPERTIES, BROMIDES, REACTION KINETICS, DISTILLATION, MOLECULAR WEIGHT, PURIFICATION, CHEMICAL ANALYSIS, VOLUMETRIC ANALYSIS, MELTING POINT, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, SPECTRUM ANALYZERS, VAPORS, DENSITY, OXIDES, HYDROLYSIS, VACUUM.

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE