Accession Number : AD0502179

Title :   Ionic Fluorine Chemistry.

Descriptive Note : Semiannual status rept. no. 4, 1 Dec 68-30 Apr 69,

Corporate Author : OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS GROUP

Personal Author(s) : Hyde,Gene A. ; Mangold,Donald J.

Report Date : 31 MAY 1969

Pagination or Media Count : 21

Abstract : This report describes further attempts to prepare the ClF6 anion. The use of large excesses (up to ClF5:CsF of 120:1) or the use of activated CsF did not result in products containing the desired anion. Conflicting reports have appeared in the literature concerning the existence of a NOF-ClF5 adduct formed at -78 degrees. An investigation of this system showed that, while mixtures of NOF and ClF5 show a negative deviation from Raoult's Law, no solid product is formed. (Author)

Descriptors :   (*FLUORINE COMPOUNDS, *IONS), REACTION KINETICS, PARTICLE SIZE, VAPOR PRESSURE, SYNTHESIS(CHEMISTRY), SOLUBILITY, GAS CHROMATOGRAPHY, HYDROLYSIS (U) *SOLID ROCKET OXIDIZERS, *LIQUID ROCKET OXIDIZERS, CHLORATES, FLUORIDES, ACETONES, CHLORINE COMPOUNDS, NITROSO COMPOUNDS, *HALOGEN COMPOUNDS, ADDITION REACTIONS, CESIUM COMPOUNDS, CHLORIDES, COMPLEX COMPOUNDS

Subject Categories : Liquid Rocket Propellants
      Solid Rocket Propellants

Distribution Statement : APPROVED FOR PUBLIC RELEASE