Accession Number : AD0509589
Title : Synthesis of Stable New Interhalogen Oxidizers.
Descriptive Note : Final rept. 3 Feb 69-2 Feb 70,
Corporate Author : STANFORD RESEARCH INST MENLO PARK CALIF
Personal Author(s) : Tolberg,Wesley E. ; Zeilenga,Gerald R. ; Rewick,Robert T. ; Dolder,Michael P.
Report Date : 28 FEB 1970
Pagination or Media Count : 43
Abstract : The study of the ClF5/SbF5/F2 system was continued in an effort to synthesize ClF6SbF6. Infrared spectroscopic data on the products of reactions in Monel reactors had been interpreted as showing the probable synthesis of ClF6(+). However, subsequent reactions in aluminum reactors established that the compound was not formed unless either copper or nickel was present. The reaction was not catalyzed by a small amount of nickel. Thus, while the possibility that the material was ClF6SbF6 cannot be completely eliminated, it now seems likely that the product was a complex metal salt.
Descriptors : (*LIQUID ROCKET OXIDIZERS, HALOGENS), SYNTHESIS(CHEMISTRY), INFRARED SPECTROSCOPY, IMPURITIES, SOLVENT EXTRACTION (U) *CHLORINE COMPOUNDS, DECOMPOSITION, FLUORINATION, FLUORINE, OXIDATION, CESIUM COMPOUNDS, PYROLYSIS, FLUORIDES, ANTIMONY COMPOUNDS, IONS, PLATINUM COMPOUNDS, ALUMINUM ALLOYS, NICKEL, HYDROLYSIS, POWDER METALS, CATALYSIS
Subject Categories : Liquid Rocket Propellants
Distribution Statement : APPROVED FOR PUBLIC RELEASE