Accession Number : AD0602060

Title :   THE BAND SPECTRUM AND DISSOCIATION ENERGY OF CLF.

Corporate Author : REDSTONE SCIENTIFIC INFORMATION CENTER REDSTONE ARSENAL ALA

Personal Author(s) : Schmitz,Heinz ; Schumacher,Hans Joachim

Report Date : 15 MAY 1964

Pagination or Media Count : 7

Abstract : The existence of absorption bands of gaseous chlorine fluoride (1.5 atm. at r.t.) between 4600 and 5300 Angstrom units was confirmed. Results are presented in pictorial and tabular form. The dissociation energy of ClF was found to be 60.3 = 0.5 kcal in the case of decomposition to excited F and normal Cl, and 58.9 = 0.5 kcal in the case of decomposition to excited Cl and normal F. Based upon these results, the dissociation energy of molecular fluorine was determined to be 33.4 kcal or 30.6 kcal, depending on whether the value 60.3 or 58.9 was used.

Descriptors :   (*CHLORINE COMPOUNDS, FLUORIDES), ABSORPTION SPECTRA, BAND SPECTRA, DISSOCIATION, THERMOCHEMISTRY, FLUORINE, EXCITATION, ATOMIC ENERGY LEVELS, WEST GERMANY

Distribution Statement : APPROVED FOR PUBLIC RELEASE