
Accession Number : AD0606146
Title : LOWER BOUNDS FOR THE HELMHOLTZ FUNCTION.
Descriptive Note : Technical rept. no. 10,
Corporate Author : BRANDEIS UNIV WALTHAM MASS
Personal Author(s) : Golden,Sideny
Report Date : 15 SEP 1964
Pagination or Media Count : 8
Abstract : A mathematical theorem is established for traces of products of bounded Hermitian and definiteoperators. This theorem is applied to the equilibrium partition function by exploiting an infinite product representation of the exponential function of the sum of two operators. As a result, a set of inequalities is established which yields a set of upper bonds for the partition function. This result is invariant to the particle statistics of the system. A general argument yields the result that the classical Helmholtz free energy function serves as a lower bound to the corresponding quantum result. (Author)
Descriptors : (*CHEMICAL EQUILIBRIUM, MATHEMATICAL ANALYSIS), (*SPECIAL FUNCTIONS (MATHEMATICAL), QUANTUM THEORY), QUANTUM STATISTICS, THERMODYNAMICS, ENERGY, POTENTIAL THEORY, OPERATORS (MATHEMATICS), CALCULUS OF VARIATIONS, HAMILTONIAN, EQUATIONS OF STATE, MATRICES(MATHEMATICS)
Distribution Statement : APPROVED FOR PUBLIC RELEASE