Accession Number : AD0611598

Title :   THE ANOMALOUS STARK EFFECT OF FLUOROFORM IN THE NU6=1 VIBRATIONAL STATE,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF PURE PHYSICS

Personal Author(s) : Costain,C. C.

Report Date : 27 OCT 1964

Pagination or Media Count : 7

Abstract : It is shown that the paper of Maes and Amat, which explains the anomalous frequencies of the NU6, J = 2 to 1, K = 0 lines in CHF3 and CDF3 by taking into account a strong mixing of K = 0 and K = 2 levels, also predicts accurately, the Stark effect of these transitions. In addition, the perturbing J = 2, K = =2, l = =1 level of the v6 = 1 vibration of CHF3 has been found at the position they predict. Further examination of the NU3 + NU6, J = 2 to 1 line has removed the uncertainty in the assignment of the NU3 + NU6 and NU2, J = 1 to 0 transitions. (Author)

Descriptors :   (*MOLECULAR SPECTROSCOPY, FLUORINE COMPOUNDS), (*FLUORINE COMPOUNDS, MOLECULAR SPECTROSCOPY), PERTURBATION THEORY, DIPOLE MOMENTS, LINE SPECTRA, ELECTRIC MOMENTS, SELECTION RULES(PHYSICS), QUANTUM THEORY, VIBRATION

Distribution Statement : APPROVED FOR PUBLIC RELEASE