Accession Number : AD0612245

Title :   THE THERMAL DECOMPOSITION OF METAL COMPLEXES. XIII. SOME TETRAMMINEPALLADIUM(II) COMPLEXES,

Corporate Author : TEXAS TECHNOLOGICAL COLL LUBBOCK

Personal Author(s) : Wendlandt,W. W. ; Funes,L. A.

Report Date : 07 FEB 1964

Pagination or Media Count : 7

Abstract : The thermal dissociation of the palladium(II) tetramminecomplexes, Pd(NH3)4X (where X is 2Cl, 2Br, 2I, 2NO3, and SO4), was studied by thermogravimetry, DTA, GE, and by analysis of the pyrolysis products. The complexes, except for the nitrate and sulphate, dissociated to give the trans-diammine-complexes, Pd(NH3)2X. The diammine-iodide and bromide complexes dissociated to give the corresponding anhydrous metal halides, PddX2. The stoicheiometry for the thermal dissociation of the Pd(NH3)2X2 complexes, where X was Cl, Br, and I, was determined. (Author)

Descriptors :   (*PYROLYSIS, COMPLEX COMPOUNDS), (*COMPLEX COMPOUNDS, PYROLYSIS), (*PALLADIUM COMPOUNDS, PYROLYSIS), (*AMMONIUM COMPOUNDS, PYROLYSIS), CHLORIDES, BROMIDES, IODIDES, NITRATES, SULFATES, THERMOCHEMISTRY, DISSOCIATION

Distribution Statement : APPROVED FOR PUBLIC RELEASE