Accession Number : AD0620328

Title :   TRIFLUOROMETHYL-SUBSTITUTED BORANES. TRIFLUOROMETHYL DI-N-BUTYLBORANE AND TRIFLUOROMETHYLBORON DIFLUORIDE.

Descriptive Note : Technical rept.,

Corporate Author : OREGON STATE UNIV CORVALLIS DEPT OF CHEMISTRY

Personal Author(s) : Parsons,Theran D. ; Self,James M. ; Schaad,Lewis H.

Report Date : 16 AUG 1965

Pagination or Media Count : 11

Abstract : The preparation and properties of trifluoromethyl di-nbutylborane and trifluoromethylboron difluoride are reported. Loss of difluorocarbene from the trifluoromethyl group bonded to electron-deficient boron was observed in the presence of catalysts but in vacuo at room temperature the substances were stable for months. Infrared spectra and vapor pressure data for n-butylboron difluoride and di-n-butylboron fluoride are reported. (Author)

Descriptors :   (*ORGANOBORANES, FLUORIDES), (*FLUORINE COMPOUNDS, BORANES), SYNTHESIS(CHEMISTRY), CHEMICAL PROPERTIES, STABILITY, DECOMPOSITION, CATALYSIS, INFRARED SPECTRA, VAPOR PRESSURE

Distribution Statement : APPROVED FOR PUBLIC RELEASE