Accession Number : AD0621222

Title :   SULFENIC ACIDS AND THEIR DERIVATIVES. XLI. SULFENYL NITRATES AND SULFINYL RADICALS,

Corporate Author : UNIVERSITY OF SOUTHERN CALIFORNIA LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Topping,Richard M. ; Kharasch,Norman

Report Date : 1965

Pagination or Media Count : 7

Abstract : Sulfenyl nitrates, RSONO2, represent a novel class of sulfenyl compounds. The preparation of the first examples is described and some of their properties are recorded. The near-quantitative conversion of sulfenyl nitrates to thiolsulfonate esters (2 RSONO2 yields RSO2SR + 2NO2) is demonstrated and interpreted as a dimerization reaction of sulfinyl radicals. (Author)

Descriptors :   (*ORGANIC SULFUR COMPOUNDS, SYNTHESIS(CHEMISTRY)), NITRATES, CHEMICAL PROPERTIES, SULFONATES, CHLORINE COMPOUNDS, NITROBENZENES, DECOMPOSITION

Distribution Statement : APPROVED FOR PUBLIC RELEASE