Accession Number : AD0621229

Title :   PEROXIDE DECOMPOSITION AND CAGE EFFECT,

Corporate Author : POLYTECHNIC INST OF BROOKLYN N Y INST OF POLYMER RESEARCH

Personal Author(s) : Braun,W. ; Rajbenbach,L. ; Eirich,F. R.

Report Date : 1961

Pagination or Media Count : 7

Abstract : The decomposition of acetyl peroxide is discussed in terms of cage theory and a rate constant for the decarboxylation of the resultant acetoxy free radical is derived.

Descriptors :   (*PEROXIDES, DECOMPOSITION), (*FREE RADICALS, PEROXIDES), REACTION KINETICS, CHEMICAL EQUILIBRIUM, PROBABILITY, RECOMBINATION REACTIONS, ESTERS, PYROLYSIS, VISCOSITY

Distribution Statement : APPROVED FOR PUBLIC RELEASE