Accession Number : AD0621611

Title :   HOMOTROPYLIUM ION AND ITS MOLYBDENUM TRICARBONYL COMPLEX,

Corporate Author : CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Winstein,S. ; Kaesz,H. D. ; Kreiter,C. G. ; Friedrich,Edwin C.

Report Date : 01 JUN 1965

Pagination or Media Count : 4

Abstract : The cyclo-octatetraene complex C8H8M0(CO)3 was prepared for the first time and some of its properties were examined. A comparison of a protonated cationic form of this complex with the related C8H9(+)Fe(CO)3 cation strongly supports nonclassical homotropylium structures for the former complex and the C8H9(+) free ion.

Descriptors :   (*COMPLEX COMPOUNDS, MOLECULAR STRUCTURE), (*FREE RADICALS, MOLECULAR STRUCTURE), (*MOLYBDENUM COMPOUNDS, COMPLEX COMPOUNDS), (*CYCLOOCTATETRAENE, COMPLEX COMPOUNDS), IONS, ATOMIC ORBITALS, NUCLEAR MAGNETIC RESONANCE, CHEMICAL BONDS

Distribution Statement : APPROVED FOR PUBLIC RELEASE