Accession Number : AD0633058

Title :   SYNTHESIS AND POLYMERIZATION OF FLUORINATED SULFUR MODIFIED NITROSO RUBBER.

Descriptive Note : Quarterly rept. no. 9, 1 Jul-26 Nov 65,

Corporate Author : PENINSULAR CHEMRESEARCH INC GAINESVILLE FLA

Personal Author(s) : Stump,Eugene C. ; Oliver,Ward H.

Report Date : 21 DEC 1965

Pagination or Media Count : 28

Abstract : Terpolymer samples containing 3 and 6 mole percent ONCF2CF2CO2CH3 with CF3NO and CF2=CF2 were prepared. A larger amount (280 g.) of 1,1,2-trifluorobutadiene terpolymer with CF3NO and CF2=CF2 was prepared. Terpolymers of CF2=CFCF2NO, CF2=CFCH2CF2CF2CH2CF=CF2 and ONCF2CF2CF2COOH with CF3NO and CF2=CF2 were prepared. Attempted copolymerization of carbonyl fluoride and hexafluoroacetone with CF3NO was unsuccessful. A 2-1. reactor equipped with stirrer and cooling coils has been procured and is being fitted with a refrigeration system. (Author)

Descriptors :   (*SYNTHETIC RUBBER, SYNTHESIS(CHEMISTRY)), (*ORGANIC NITROGEN COMPOUNDS, POLYMERIZATION), (*ORGANIC SULFUR COMPOUNDS, POLYMERIZATION), FLUORINE COMPOUNDS, HALOGENATED HYDROCARBONS, BUTADIENES, ETHYLENES, PROPENES, INFRARED SPECTRA

Subject Categories : Organic Chemistry
      Elastomers and Rubber

Distribution Statement : APPROVED FOR PUBLIC RELEASE