Accession Number : AD0637556
Title : BASIC INVESTIGATIONS IN PHOTOPOTENTIOMETRY.
Descriptive Note : Technical rept. 1 May 65-30 Apr 66.
Corporate Author : MIDWEST RESEARCH INST KANSAS CITY MO
Personal Author(s) : Rosebrook,Donald D.
Report Date : JUL 1966
Pagination or Media Count : 36
Abstract : A photopotentiometry system was devised and successfully operated. The photopotentials measured in the tris(oxalato)ferrate(III) system compare favorably with potentials calculated from the Nernst equation. The potentials are produced by a mechanism resembling a concentration cell with transference. The effects of temperature and concentration are well defined by the Nernst equation. The observed potential at any time during the irradiation is approximated by a potential calculated from the Nernst equation. (Author)
Descriptors : (*PHOTOCHEMICAL REACTIONS, REACTION KINETICS), (*ELECTROCHEMISTRY, REACTION KINETICS), (*COMPLEX COMPOUNDS, PHOTOCHEMICAL REACTIONS), OXALATES, FERRATES, CHEMICAL ANALYSIS, CONCENTRATION(CHEMISTRY), CHEMICAL EQUILIBRIUM
Subject Categories : Physical Chemistry
Radiation and Nuclear Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE