Accession Number : AD0639498

Title :   SOME TERTIARY ALCOHOLS DERIVED FROM M-CARBORANE.

Descriptive Note : Technical rept.

Corporate Author : OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS DIV

Personal Author(s) : Obenland,Clayton ; Papetti,Stelvio

Report Date : SEP 1966

Pagination or Media Count : 8

Abstract : A report is given of the preparation of several tertiary diols of m-carborane, such as B10H10C2(CH3)2OH)2 and their fluorinated derivatives such as B10H10C2(C(CF3)2OH)2. These were prepared by reaction of the dilithio salt of m-carborane with the appropriate ketone. The following compounds were prepared - M-carboranyl-1,7-bis (dimethylcarbinol); m-carboranyl-1,7-bis(methyl trifluoro-methyl carbinol); m-carboranyl-1,7-bis (di-trifluoromethyl carbonol); m-carboranyl-1,7-bis(chloro difluoromethyl trifluoromethyl carbinol).

Descriptors :   (*ORGANOBORANES, *ALCOHOLS), FLUORINE COMPOUNDS, CHLORINE COMPOUNDS, GLYCOLS, KETONES, CHEMICAL REACTIONS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE