Accession Number : AD0646013

Title :   TRANSITION METAL COMPLEXES WITH TWO NEW SERIES OF TETRADENTATE LIGANDS.

Descriptive Note : Final rept., 1 Oct 63-30 Sep 66,

Corporate Author : OHIO STATE UNIV RESEARCH FOUNDATION COLUMBUS

Personal Author(s) : Meek,Devon W.

Report Date : 14 NOV 1966

Pagination or Media Count : 11

Abstract : An investigation was undertaken of the coordinating properties of flexible tetradentate phosphorus, arsenic, and nitrogen ligands of the type D(CH2CH2CH2D')3, (where D does not = D'). A series of nickel (II) complexes with the five coordinate (Ni(ligand)X)(+) cations was isolated and studied extensively. A number of Pd(II) and Co(II) complexes were also examined. A second series of studies involved the nature of bonding in boron-transition metal complexes having groups of the type B(OCH2CH2NR2). Also, the synthesis of a number of tetradentate compounds with boron-carbon bonds was undertaken (e.g., B(Ph-AsO2)3).

Descriptors :   (*COMPLEX COMPOUNDS, *TRANSITION METALS), (*ORGANOBORANES, COMPLEX COMPOUNDS), (*NICKEL COMPOUNDS, COMPLEX COMPOUNDS), PHOSPHORUS COMPOUNDS, ARSENIC COMPOUNDS, NITROGEN COMPOUNDS, STEREOCHEMISTRY, MOLECULAR ASSOCIATION, CHEMICAL BONDS, PALLADIUM COMPOUNDS, COBALT COMPOUNDS

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE