Accession Number : AD0646745

Title :   BASIC RESEARCH ON SYNTHESIS OF NEW PHOSPHORUS-NITROGEN REAGENTS.

Descriptive Note : Interim rept. 15 Nov 64-15 Nov 65,

Corporate Author : MONSANTO RESEARCH CORP DAYTON OHIO

Personal Author(s) : Nielsen,Morris L.

Report Date : JAN 1966

Pagination or Media Count : 28

Abstract : Two compounds of the general formula (RO)2P-ONHP-O(OR)2 were prepared and applied in the preparation of metal derivatives. Tetraethyl imidodiphosphate and tetraphenyl imidodiphosphate were prepared by published methods. New crystalline derivatives were obtained for the first compound with zinc, for the second compound with zinc, palladium, lanthanum, cerium, praseodymium and europium. A tetramminepalladium (II) derivative of tetraphenyl imidodiphosphate is promising for the gravimetric determination of palladium. (Author)

Descriptors :   (*COMPLEX COMPOUNDS, SYNTHESIS), (*PHOSPHORUS COMPOUNDS, SYNTHESIS), (*NITROGEN COMPOUNDS, SYNTHESIS), METALS, GRAVIMETRIC ANALYSIS

Subject Categories : Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE