Accession Number : AD0647810

Title :   1,2-BIS(SUBSTITUTED)-O-CARBORANE COMPLEXES. II. NICKEL(II) AND COBALT(II) COMPLEXES DERIVED FROM THE LIGAND 1,2-BIS(MERCAPTO)-O-CARBORANE.

Descriptive Note : Technical rept.,

Corporate Author : OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS GROUP

Personal Author(s) : Smith,H. D. , Jr. ; Robinson,Martin A. ; Papetti,S.

Report Date : FEB 1967

Pagination or Media Count : 21

Abstract : Some nickel(II) and cobalt(II) salts have been found to react readily with 1,2-bis(mercapto)-o-carborane in the presence of stabilizing phosphorous ligands or the tetraethylammonium cation to yield square planar MS2P2 and MS4(2) complexes. Electronic spectra of the nickel complexes are discussed. (Author)

Descriptors :   (*ORGANOBORANES, *COMPLEX COMPOUNDS), (*NICKEL COMPOUNDS, COMPLEX COMPOUNDS), (*COBALT COMPOUNDS, COMPLEX COMPOUNDS), SYNTHESIS, SALTS, SPECTROSCOPY

Subject Categories : Organic Chemistry
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE