
Accession Number : AD0651428
Title : A HILBERT SPACE DERIVATION OF THE CLASSICAL GENERALIZED MASTER EQUATION,
Corporate Author : NAVAL RADIOLOGICAL DEFENSE LAB SAN FRANCISCO CALIF
Personal Author(s) : Leaf,B. ; Schieve,W. C.
Report Date : 29 MAR 1967
Pagination or Media Count : 38
Abstract : The ketvector notation of Dirac is used to formulate the classical Liouville equation in a Hilbert space of functions spanned by the eigenkets of the Liouville operator. The formalism applies to finite as well as infinte systems. The solutions of the inhomogeneous Liouville equation is considered where the inhomogeneity is taken as the perturbation. The Hilbert space formalism allows the introduction of projection operators, and the derivation of the generalized master equations without perturbation theory. In the weak coupling limit this is shown to reduce to the BroutPrigogine equation. A thermodynamic interpretation is given to spacially inhomogeneous terms in the equation. (Author)
Descriptors : (*HILBERT SPACE, *STATISTICAL MECHANICS), INTEGRAL TRANSFORMS, OPERATORS(MATHEMATICS)
Subject Categories : Physical Chemistry
Theoretical Mathematics
Distribution Statement : APPROVED FOR PUBLIC RELEASE