Accession Number : AD0657174

Title :   DEUTERIUM ISOTOPE STUDIES ON 2,3-DICARBAHEXABORANE(8).

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA STATE COLL LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Spielman,John R. ; Warren,Richard ; Dunks,Gary B. ; Scott,James E. , Jr. ; Onak,Thomas

Report Date : 01 AUG 1967

Pagination or Media Count : 11

Abstract : Deuterium exchange at various positions on the C2B4H8 molecule was studied. D2 exchanges with all boron-bonded hydrogen atoms, and B2D6 in the presence of diglyme exchanges only at the 4-, 6-terminal positions. The (CH3)2C2B4H6-DCl exchange, catalyzed by aluminum chloride, occurs at both apex and base terminal positions. C,C-Dideuterio-2,3-dicarbahexaborane(8), D2C2B4H6, was prepared for comparison of the infrared spectrum. (Author)

Descriptors :   (*BORANES, EXCHANGE REACTIONS), (*DEUTERIUM COMPOUNDS, BORANES), DEUTERIUM, HYDROGEN, CATALYSIS, SYNTHESIS(CHEMISTRY), INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE