Accession Number : AD0662390

Title :   PENTAFLUOROSULFUR CARBONYL FLUORIDE, PENTAFLUOROSULFUR FLUOROFORMATE AND PENTAFLUOROSULFUR PEROXOFLUOROFORMATE.

Descriptive Note : Technical rept.,

Corporate Author : WASHINGTON UNIV SEATTLE

Personal Author(s) : Czerepinski,Ralph ; Cady,George H.

Report Date : NOV 1967

Pagination or Media Count : 34

Abstract : The compounds SF5CFO, SF5OCFO and SF5OOCFO were produced in low yields by ultraviolet irradiation of the following mixtures, respectively: (1) S2F10 and C2O2F2; (2) SF5OF and C2O2F2; (3) SF5OOSF5, and C2O4F2. Each of the new compounds reacts readily with a solution of sodium hydroxide, and has infrared and 19F NMR spectra in keeping with its structure. (Author)

Descriptors :   (*OXIDIZERS, SYNTHESIS(CHEMISTRY)), (*FLUORINE COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*SULFUR COMPOUNDS, SYNTHESIS(CHEMISTRY)), HALOGENATED HYDROCARBONS, FORMATES, PHOTOCHEMICAL REACTIONS, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, FREE RADICALS, PEROXIDES, OXYFLUORIDES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE