Accession Number : AD0663240

Title :   RESEARCH IN SYNTHESIS AND CHARACTERIZATION OF HIGHLY ARYLATED ORGANOSILICON COMPOUNDS.

Descriptive Note : Final rept.,

Corporate Author : STAUFFER CHEMICAL CO ADRIAN MICH SILICONE DIV

Personal Author(s) : Pande,K. C. ; Hart,G. M. ; Ezell,J. W. ; Gudemoos,S. R. ; Smith,D. C.

Report Date : JUL 1967

Pagination or Media Count : 23

Abstract : A series of six organomonofluorosilanes was prepared via the corresponding chlorosilane analogs by derivatization of the appropriate chlorosilane intermediates with 1-naphthyllithium followed by rehalogenation with a suitable inorganic fluoride. Aqueous hydrofluoric acid (10%) was used in all but the single case of an Si-H-containing compound for which a hexafluorosilicic acid reagent was found to be satisfactory. (Author)

Descriptors :   (*SILANES, SYNTHESIS(CHEMISTRY)), (*FLUORINE COMPOUNDS, SILANES), FLUORINATION, AROMATIC COMPOUNDS, POLYCYCLIC COMPOUNDS, CHEMICAL ANALYSIS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE