Accession Number : AD0673273

Title :   ORGANIC REACTIONS IN THE SOLID STATE AND IN SOLID SOLUTIONS.

Descriptive Note : Final technical rept. Mar 67-Feb 68,

Corporate Author : HEBREW UNIV JERUSALEM (ISRAEL) DEPT OF ORGANIC CHEMISTRY

Personal Author(s) : Patai,Saul

Report Date : MAR 1968

Pagination or Media Count : 24

Abstract : Investigations are reported on the transacylation reaction between organic amides and organic acids. Emphasis was placed on obtaining exact kinetic data in order to determine the main effects influencing the reaction in the neat state and comparing the effects of various substituents on the acyl and aryl moieties of the acyl anilides with what would be expected from similar substituents in solvent systems. Kinetic measurements were performed on the reactions of phthalic acid and acetanilide, various acyl anilides, and ring-substituted acetanilides. Exploratory experiments were also performed between ring-substituted acetanilides and succinic, glutaric, maleic and fumaric acids. The influence of imidazole as a catalyst of the transacylation reaction of phthalic anhydride and acetanilide is also reported. (Author)

Descriptors :   (*REACTION KINETICS, SOLIDS), (*SOLID SOLUTIONS, CHEMICAL REACTIONS), AMIDES, CARBOXYLIC ACIDS, NITROGEN HETEROCYCLIC COMPOUNDS, PHTHALIC ACIDS, CATALYSTS, SUCCINIC ACID, GLUTARIC ACID, ACETAMIDES, DIBASIC ORGANIC ACIDS, GAS CHROMATOGRAPHY, ISRAEL

Subject Categories : Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE