Accession Number : AD0673549

Title :   SYNTHESIS OF NOVEL SUBSTITUTED (3)-1,7-DICARBAUNDECABORATE(12) IONS FROM 1,8-DICARBACLOSOUNDECABORANE(11) AND CARBANIONS.

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s) : Hawthorne,M. Frederick ; Owen,David A.

Report Date : 17 JUL 1968

Pagination or Media Count : 15

Abstract : The reaction of the B9C2H11 carborane and its C-substituted derivatives with carbanions, derived from a series of closo-carboranes by C-H ionization, react to form anions in which the two carborane systems are mutually bonded. The product anions are considered to be B-substituted derivatives of the (3)-1, 7-B9C2H12(-) ion. (Author)

Descriptors :   (*BORANES, IONIZATION), (*BORATES, SYNTHESIS(CHEMISTRY)), CARBON COMPOUNDS, IONS, MOLECULAR STRUCTURE, NUCLEAR MAGNETIC RESONANCE

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE