Accession Number : AD0674385

Title :   RATES OF OZONE-OLEFIN REACTIONS IN CARBON TETRACHLORIDE SOLUTIONS,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF APPLIED CHEMISTRY

Personal Author(s) : Williamson,D. G. ; Cvetanovic,R. J.

Report Date : 22 JAN 1968

Pagination or Media Count : 6

Abstract : The values of the second-order rate constants (k1) for the reactions of ozone with a number of simple alkenes were determined at room temperature. The rates vary with olefin structure in a manner very similar to that found previously in this laboratory for the vapor-phase reactions of ozone with olefins. The results, therefore, confirm the vastly different behavior from the one observed in air-pollution studies at very low reactant concentrations. The reason for the difference is not clear. (Author)

Descriptors :   (*ALKENES, REACTION KINETICS), (*OZONE, REACTION KINETICS), OZONIDES, SYNTHESIS(CHEMISTRY), SOLVENTS, CARBON TETRACHLORIDE, CANADA

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE