Accession Number : AD0678471

Title :   INVESTIGATION OF STRUCTURE OF FERROCENE AND FERRICYANIUM BY MEANS OF X-RAY K-ABSORPTION SPECTRA,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Vainshtein,E. E. ; Kopelev,Yu. F. ; Kotlyar,B. I.

Report Date : 21 DEC 1967

Pagination or Media Count : 10

Abstract : An x-ray spectrograph with quartz crystal (1340 planes) was used to investigate the K absorption edge of iron in Fe(C5H5)2 and Fe(C5H5)2Cl. The calculation of the absorption edge was carried out under the assumption that the system is hydrogen-like. The influence of the electric field of the molecule on the hydrogen-like system is disclosed, and the effective charge of the iron ion in the investigated compound is found to be +0.7. (Author)

Descriptors :   (*FERROCENES, *X RAY ABSORPTION ANALYSIS), ELECTRON DENSITY, MOLECULAR ORBITALS, MOLECULAR STRUCTURE, CHEMICAL BONDS, USSR, CYANIDES

Subject Categories : Organic Chemistry
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE