Accession Number : AD0679765

Title :   NOVEL SIGMA-BONDED TRANSITION METAL CARBORANE COMPLEXES.

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s) : Smart,James C. ; Garrett,Philip M. ; Hawthorne,M. Frederick

Report Date : 25 NOV 1968

Pagination or Media Count : 9

Abstract : Reactions of 1,2-B10C2H11(-) and 1,10-B8C2H8(-2) ions with ((Pi-C5H5)Fe(CO2))2 in ether solvents produces sigma-bonded iron carborane complexes. The two complexes reported are 1-((pi-C5H5)Fe(CO2)-2-(CH3)-(sigma-1,2-B10C2H10)) and 1,10-((pi-C5H5)Fe(CO)2)2 - 1,10-(sigma-B8C2H8) which were prepared in 47 and 71% yield, respectively. (Author)

Descriptors :   (*ORGANOBORANES, *METAL CARBONYLS), (*COMPLEX COMPOUNDS, ORGANOBORANES), IRON COMPOUNDS, SYNTHESIS(CHEMISTRY), IONS

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE