Accession Number : AD0681267

Title :   THE CHARGE ON ATOMS IN FERROCENE AND ITS ANALOGS,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Batsanov,S. S.

Report Date : 26 APR 1968

Pagination or Media Count : 10

Abstract : From molecular orbital calculations and from previously published experimental data the positive charge of the metal atom and the distribution of negative charges on the rings are given for M(C5H5)2, where M is Mg, Ti, Sn, Pb, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt; M(C5H5)3 where M is Al, Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, U, As, Sb, Bi; M(C6H6)2 where M is V, Cr, Mo, W, Fe, Ni, Ru, Pd, Pt; M(C5H5)2Cl and M(C5H5)2NO3 where M is U, Ti, V, Cr, Mn, Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt. The data should make possible further calen. of the strength of the metal-ring bonds. (Author)

Descriptors :   (*MOLECULAR ORBITALS, *FERROCENES), ELECTRON DENSITY, IONS, CHEMICAL BONDS, USSR

Subject Categories : Organic Chemistry
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE