Accession Number : AD0681940

Title :   SYNTHESES, REACTIONS, AND STRUCTURES OF CERTAIN SULFUR-NITROGEN COMPOUNDS.

Descriptive Note : Final rept. 1 Sep 62-31 Dec 68,

Corporate Author : ILLINOIS UNIV URBANA NOYES CHEMICAL LAB

Personal Author(s) : Moeller,Therald

Report Date : 31 JAN 1969

Pagination or Media Count : 22

Abstract : Sulfamide was shown to undergo condensation with monoketones to yield new carbon-nitrogen-sulfur heterocyclic compounds, to undergo condensation to various simple and methyl-substituted linear deammonation products some of which in turn formed trisubstituted phosphazo derivatives, and to form weak complexes of several types with various transition metal ions, notably Cu(2+). Alpha- and beta-Sulfanuric chloride trimers were synthesized, separated, and investigated by structure-indicating techniques. Alpha-Sulfanuric chloride was found to undergo ring cleavage with strong nucleophides, to yield isomeric substitution products with the more weakly basic morpholine, and to yield 'cis' and 'trans' fluorides. 'Cis' sulfanuric fluoride trimer has been converted to a number of isomeric phenylated and aminolyzed substitution products, all of which have been isolated and evaluated by infrared and nuclear magnetic resonance spectroscopy. The reactions of trichlorophosphazo-substituted phosphonitrilic chloride trimers with phenyl Grignard reagents have been explored and the products characterized similarly. (Author)

Descriptors :   (*ORGANIC SULFUR COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*ORGANIC NITROGEN COMPOUNDS, SYNTHESIS(CHEMISTRY)), CHEMICAL REACTIONS, MOLECULAR STRUCTURE, AMIDES, NITROGEN HETEROCYCLIC COMPOUNDS, SULFUR HETEROCYCLIC COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, PHOSPHORUS HETEROCYCLIC COMPOUNDS, COMPLEX COMPOUNDS, COPPER COMPOUNDS, POLYMERS, FLUORINE COMPOUNDS, CONDENSATION REACTIONS, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, CRYSTAL STRUCTURE, CHEMICAL BONDS, AMINES

Subject Categories : Polymer Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE