Accession Number : AD0682823

Title :   THE USE OF CORRELATION EQUATIONS TO DESCRIBE THE INTERACTION OF SUBSTITUENTS WITH THE FERROCENYL NUCLEUS,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Perevalova,E. G. ; Gubin,S. P. ; Nesmeyanov,A. N.

Report Date : 09 FEB 1968

Pagination or Media Count : 22

Abstract : A systematic correlation analysis was conducted on the quantitative data about the effect of substituents on the reversible oxidation of substituted ferrocenes. The character of interaction between the substituents, the five-member aromatic ring and the iron nucleus as the reaction center in the oxidation of monosubstituted ferrocenes was studied. A clarification was made of certain pecularities of the iron atom as a reaction center in this reaction. (Author)

Descriptors :   (*FERROCENES, *OXIDATION REDUCTION REACTIONS), REACTION KINETICS, MOLECULAR ORBITALS, CHEMICAL BONDS, ALKANES, ETHERS, HALIDES, USSR

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE