Accession Number : AD0684555

Title :   STUDIES IN STEREOCHEMISTRY.

Descriptive Note : Final rept. 1 Jul 66-31 Jul 68,

Corporate Author : PRINCETON UNIV N J DEPT OF CHEMISTRY

Personal Author(s) : Mislow,Kurt

Report Date : MAR 1969

Pagination or Media Count : 16

Abstract : A summary is given of research effort which involved a comparative study of sulfur and phosphorus, whose stereochemistry is as yet relatively unexplored. It includes the stereochemistry of the Grignard synthesis of sulfoxides and phosphine oxides, the stereomutation of sulfoxides, structural analysis by optical methods, and studies in conformational analysis.

Descriptors :   (*SULFOXIDES, STEREOCHEMISTRY), (*PHOSPHINE OXIDES, STEREOCHEMISTRY), (*GRIGNARD REACTIONS, *STEREOCHEMISTRY), MOLECULAR STRUCTURE, MOLECULAR ROTATION, NUCLEAR MAGNETIC RESONANCE

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE