Accession Number : AD0685780

Title :   STRUCTURE OF FRIEDEL-CRAFTS INTERMEDIATES.

Descriptive Note : Final rept. Sep 66-Aug 67,

Corporate Author : MONSANTO RESEARCH CORP DAYTON OHIO

Personal Author(s) : Shirk,James S. ; Wood,J. L.

Report Date : FEB 1969

Pagination or Media Count : 29

Abstract : The acetyl chloride-aluminum chloride complex is shown to be normal Lewis acid-carbonyl complex with coordination through the oxygen. Infrared bands previously ascribed to CH3CO(+) in this system are most likely due to decomposition or reaction products. (Author)

Descriptors :   (*FRIEDEL CRAFTS REACTIONS, *MOLECULAR STRUCTURE), (*COMPLEX COMPOUNDS, FRIEDEL CRAFTS REACTIONS), (*ALUMINUM COMPOUNDS, FRIEDEL CRAFTS REACTIONS), CHLORIDES, INFRARED SPECTRA, ACETIC ACID, BENZOIC ACIDS, KETONES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE