Accession Number : AD0686062

Title :   FORMATION OF 2, 3-EPOXY PERFLUOROPROPIONYL FLUORIDE FROM THE MERCURY PHOTOSENSITIZED OXIDATION OF 1, 3-PERFLUOROBUTADIENE.

Descriptive Note : Technical rept. Feb-Jun 67,

Corporate Author : AEROSPACE CORP EL SEGUNDO CALIF LAB OPERATIONS

Personal Author(s) : Stuckey,Wayne ; Heicklen,Julian ; Knight,Vester

Report Date : 02 JAN 1969

Pagination or Media Count : 13

Abstract : A study was made of the mercury photosensitized oxidation of 1,3-C4F6 to form nearly equal amounts of CF2O and a new compound, 2,3-epoxyperfluoropropionyl fluoride, and smaller amounts of c-C3F4. The infrared and mass spectra of 2,3-epoxyperfluoropropionyl fluoride are presented. (Author)

Descriptors :   (*BUTADIENES, OXIDATION), (*PHOTOCHEMICAL REACTIONS, BUTADIENES), FLUORINE COMPOUNDS, HALOGENATED HYDROCARBONS, MERCURY, KETONES, CYCLOPROPANES, SYNTHESIS(CHEMISTRY), OXYGEN HETEROCYCLIC COMPOUNDS, MASS SPECTROSCOPY, INFRARED SPECTRA, MOLECULAR ORBITALS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE