Accession Number : AD0686429

Title :   REACTION OF THE CHLORINE-FLUORINE INTERHALOGENS WITH HYDROGEN.

Descriptive Note : Phase rept. Sep 68-Jan 69,

Corporate Author : AIR FORCE ROCKET PROPULSION LAB EDWARDS AFB CALIF

Personal Author(s) : Jaye,Fredric C. ; Blauer,Jay A.

Report Date : APR 1969

Pagination or Media Count : 21

Abstract : The reactions of ClF5, ClF3, and ClF with an excess of H2 were studied over the temperature range 351 to 525K in a gas-phase-flow reactor. The activation energy for each reaction is in each case approximately one half the interhalogen dissociation activation energy. The relationship between reactive stream separation and similar gas-phase reaction is shown. Calculated values are reported respectively for the H + ClF5, ClF3, and ClF exchange rate constants. (Author)

Descriptors :   (*CHLORINE COMPOUNDS, *COMBUSTION), (*FLUORIDES, COMBUSTION), HYDROGEN, REACTION KINETICS, BOUNDARY LAYER, LIQUID ROCKET PROPELLANTS

Subject Categories : Physical Chemistry
      Crystallography

Distribution Statement : APPROVED FOR PUBLIC RELEASE