Accession Number : AD0690567

Title :   MEDIUM EFFECTS ON ACID-CATALYZED REACTIONS.

Descriptive Note : Final rept. 1 Jan 64-31 Dec 67,

Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s) : Schubert,William M.

Report Date : 28 APR 1969

Pagination or Media Count : 36

Abstract : This is a final report on a project which included studies medium effects on protonated activated complexes. The probing devices were reactions in which both ground state and activated complex contain a single proton. In the search for suitable systems to evaluate medium effects on protonated activated complexes, a number of other reactions were studied in considerable detail. These included hydration of styrenes, as well as hydrolysis of 1-aminosulfides, 1-aminoethers, iminium ions, and cyclic acetals. (Author)

Descriptors :   (*ORGANIC SOLVENTS, *REACTION KINETICS), (*ACID BASE EQUILIBRIUM, ORGANIC SOLVENTS), (*ACETALS, HYDROLYSIS), (*STYRENES, HYDROLYSIS), CATALYSTS, SULFIDES, AMINES, ETHERS, IONS, WATER, ORGANIC SULFUR COMPOUNDS, ACETIC ACID, FLUORINE COMPOUNDS, PYRIDINES, QUINOLINES

Subject Categories : Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE