Accession Number : AD0693303
Title : GENERATION AND PROPERTIES OF IMINIUM CATIONS AND RELATED ELECTRON-DEFICIENT NITROGEN INTERMEDIATES.
Descriptive Note : Final rept. 1 Sep 66-31 Aug 69,
Corporate Author : STATE UNIV OF NEW YORK BUFFALO DEPT OF CHEMISTRY
Personal Author(s) : Lansbury,Peter T.
Report Date : SEP 1969
Pagination or Media Count : 7
Abstract : Iminium cations can be generated by ionization of oxime polyphosphates of rigid ketones incapable of rearrangement and fragmentation. This report summarizes a research effort to determine whether singlet or triplet ions are involved as intermediates in appropriate compounds when they react to produce C-H insertion and non-stereospecific rearrangement products. Another goal of this research was to find substrates where remote intramolecular nucleophilic attack at nitrogen would supercede the conventional Beckmann isomerization. (Author)
Descriptors : (*IMINES, CHEMICAL REACTIONS), (*OXIMES, CHEMICAL REACTIONS), IONIZATION, MOLECULAR ENERGY LEVELS, STEREOCHEMISTRY, THIOPHENES, NITROGEN HETEROCYCLIC COMPOUNDS
Subject Categories : Organic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE