Accession Number : AD0694185

Title :   INTERACTION OF BENZOYL- AND, 1,1'-DIBENZOYLFERROCENE WITH ACETYLENE IN THE PRESENCE OF SODIUM AMIDE IN LIQUID AMMONIA,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Vishnyakove,T. P. ; Maryashkin,N. Ya. ; Elyashberg,M. E. ; Melnikov,I. A. ; Zadko,I. I.

Report Date : 07 MAY 1969

Pagination or Media Count : 8

Abstract : The compound alpha-oxy-alpha-phenylpropynylferrocene (alpha-ferrocenyl-p-ethynyl benzyl alcohol) was synthesized with a yield of 70 percent by the reaction of benzoylferrocene with acetylene in the presence of sodium amide in liquid ammonia. Two new ferrocene derivatives were synthesized from 1,1'-dibenzoylferrocene and acetylene in the presence of sodium amide: 1-benzoyl-1' - (alpha-oxy-alpha-phenylpropynyl) ferrocene (54 percent) and 1,1' -di(alpha-oxy-alpha-phenylpropynyl) ferrocene (55 percent). The physicochemical constants were determined for all of the initially obtained compounds and their IR spectra were taken. (Author)

Descriptors :   (*FERROCENES, CHEMICAL REACTIONS), (*BENZALDEHYDES, *REDUCTION(CHEMISTRY)), (*ALKYNES, CHEMICAL REACTIONS), AMMONIA, SOLVENTS, INFRARED SPECTRA, SYNTHESIS(CHEMISTRY)

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE