Accession Number : AD0695051
Title : MAGNETIC AND OPTICAL STUDIES OF CUBIC SINGLE CRYSTALS CONTAINING 4d AND 5d IONS.
Descriptive Note : Final technical rept. 1 Jun 66-1 Jun 69,
Corporate Author : BRANDEIS UNIV WALTHAM MASS
Personal Author(s) : Dorain,Paul B.
Report Date : JUN 1969
Pagination or Media Count : 167
Abstract : The optical spectra of Os(+4) and Ru(+4) in single cubic crystals of K2PtCl6 and Cs2ZrCl6 at 4.2 degrees K is reported. The results are analysed in terms of a complete d4 intermediate coupling scheme. Magnetic susceptibilities were calculated and the magnetic moments for all excited states were calculated. A report on a calculation of the intensities for these materials is included. Tables of wavefunctions and magnetic moments for the d4 system are given. (Author)
Descriptors : (*TRANSITION METALS, *INFRARED SPECTRA), (*OSMIUM COMPOUNDS, INFRARED SPECTRA), (*RUTHENIUM COMPOUNDS, INFRARED SPECTRA), COMPLEX COMPOUNDS, SINGLE CRYSTALS, ATOMIC ENERGY LEVELS, MAGNETIC MOMENTS, WAVE FUNCTIONS, CHLORIDES, CESIUM COMPOUNDS, PLATINUM COMPOUNDS, POTASSIUM COMPOUNDS, ZIRCONIUM COMPOUNDS, CRYOGENICS
Subject Categories : Atomic and Molecular Physics and Spectroscopy
Solid State Physics
Distribution Statement : APPROVED FOR PUBLIC RELEASE