Accession Number : AD0695332

Title :   EFFECT OF SUBSTITUENTS ON REACTIVITY OF THE IRON ATOM IN FERROCENE DERIVATIVES,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Perevalova,E. G. ; Gubin,S. P.

Report Date : 08 APR 1969

Pagination or Media Count : 15

Abstract : The Redox potentials of 60 monosubstituted ferrocene derivatives were determined by means of potentiometric titration. The corresponding logarithms of equilibrium constants were correlated to the values of Hammett's and Taft's constants. The interaction of some substituents with the Fe-atom is interpreted in terms of field-effect. (Author)

Descriptors :   (*FERROCENES, *OXIDATION REDUCTION REACTIONS), (*ELECTROCHEMISTRY, FERROCENES), AROMATIC COMPOUNDS, USSR

Subject Categories : Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE