Accession Number : AD0695705

Title :   TRANSANNULAR INTERACTIONS OF HETERO ATOMS IN MEDIUM-SIZED HETEROCYCLIC COMPOUNDS.

Descriptive Note : Rept. no. 5 (Final), 1 Jun 66-30 May 69

Corporate Author : OHIO STATE UNIV COLUMBUS DEPT OF CHEMISTRY

Personal Author(s) : Paquette,Leo A.

Report Date : 15 SEP 1969

Pagination or Media Count : 12

Abstract : An examination was made of the role which heterocyclic atoms, strategically located in medium-sized rings, play in reactions which are known from related carbocyclic systems to proceed with a high degree of carbonium ion character. Research centered on the following topics: Acid-promoted rearrangements involving transannular ether oxygen participation; brosylate acetolysis; and photoisomerization of selected 3-cycloheptenone derivatives. (Author)

Descriptors :   (*CYCLOALKENES, *PHOTOLYSIS), (*OXYGEN HETEROCYCLIC COMPOUNDS, CHEMICAL REACTIONS), (*KETONES, CHEMICAL REACTIONS), CHLORINE COMPOUNDS, BROMINE COMPOUNDS, HALOGENATED HYDROCARBONS, ACETATES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE