Accession Number : AD0698043

Title :   HIGH TEMPERATURE REACTIONS OF SUBSTITUTED PYRROLES.

Descriptive Note : Final rept. 1 Sep 65-30 Sep 69,

Corporate Author : KENTUCKY RESEARCH FOUNDATION LEXINGTON

Personal Author(s) : Patterson,John M.

Report Date : SEP 1969

Pagination or Media Count : 10

Abstract : Research was undertaken to elucidate product formation and the reaction path followed in the thermally-induced isomerization of N-substituted pyrroles. Various parameters such as the effect of substituents (pyrrole-ring substituents and migrating-group substituents) on migration aptitudes, on product distribution and on reaction rate were investigated. The study of a reaction in which the potential migrating group is optically active was proposed in order to determine the nature of migration process. (Author)

Descriptors :   (*PYRROLES, *MOLECULAR ISOMERISM), STEREOCHEMISTRY, REACTION KINETICS, PYROLYSIS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE