Accession Number : AD0698434

Title :   REACTIONS OF OZONIDES. VIII. AN EXAMINATION OF THE POSSIBILITY OF REVERSIBLE OZONIDE FORMATION USING 14C LABELLING,

Corporate Author : ROYAL MILITARY COLL OF CANADA KINGSTON (ONTARIO) DEPT OF CHEMISTRY AND CHEMICAL ENGINEERING

Personal Author(s) : Kerur,Dundappa R. ; Diaper,Dennis G. M.

Report Date : 15 MAY 1968

Pagination or Media Count : 5

Abstract : Carboxyl-14C-10 formyldecanoic acid was made by 14CO2 carbonation of 10-undecenylmagnesium bromide and ozonlysis of the product. Little incorporation of label in the re-isolated ozonide was found, and it was concluded that under normal ozonolysis conditions the formation of ring ozonide is essentially irreversible. Slight incorporation in chlorofomr is explicable either by rversal of the Criegee mechanism of ozonide formation or by reversal of the recently suggested regenerative carbonyl - primary ozonide reactions. (Author)

Descriptors :   (*OZONIDES, CHEMICAL REACTIONS), (*ALDEHYDES, CHEMICAL REACTIONS), CHEMICAL EQUILIBRIUM, LABELED SUBSTANCES, KETONES, ESTERS, CANADA

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE