Accession Number : AD0700784

Title :   HIGH PRESSURE INORGANIC AND ORGANOMETALLIC SYNTHESES.

Descriptive Note : Final rept. 1 Feb 65-31 Aug 69,

Corporate Author : PENNSYLVANIA UNIV PHILADELPHIA DEPT OF CHEMISTRY

Personal Author(s) : MacDiarmid,Alan G. ; Hagen,Arnulf P. ; Broudy,Philip M.

Report Date : 30 SEP 1969

Pagination or Media Count : 12

Abstract : A summary of the author's publications and results are given on the use of high pressures in synthesizing compounds such as F3SiCo(CO)4, OPF3, SPF3, etc. Syntheses of compounds such as 2(Bu4N)(+), (SiF4Cl2)(-2), and Cl2Si(2,2'-dipyridyl)2 have also been carried out. Physical, spectroscopic, structural and chemical properties of the compounds have been investigated in detail and are described. (Author)

Descriptors :   (*INORGANIC COMPOUNDS, *HIGH PRESSURE), (*METAL CARBONYLS, SYNTHESIS(CHEMISTRY)), (*PHOSPHORUS COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*SILANES, CHEMICAL REACTIONS), SULFUR COMPOUNDS, FLUORIDES, COBALT COMPOUNDS, OXYGEN COMPOUNDS, IONS, SILICATES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE